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HOME > J Korean Powder Metall Inst > Volume 18(3); 2011 > Article
폐 WC-Co계 초경합금에서 추출된 코발트 재생 원료를 이용한 LiCoO2 입자 합성 연구
양희승, 피재환, 김유진
Synthesis of LiCoO2 Powders using Recycled Cobalt Precursors from Waste WC-Co Hard Metal
Hee-Seung Yang, Jae-Hwan Pee, Yoo-Jin Kim
Journal of Korean Powder Metallurgy Institute 2011;18(3):277-282
DOI: https://doi.org/10.4150/KPMI.2011.18.3.277
1한국세라믹기술원 엔지니어링 세라믹센터
2한국세라믹기술원 도자기술센터
3한국세라믹기술원 엔지니어링 세라믹센터
1Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology
2Ceramicware Technology Center, Korea Institute of Ceramic Engineering and Technology
3Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology
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[ LiCoO_2 ] a cathode material for lithium rechargeable batteries, was prepared using recycled Co_3O_4. First, the cobalt hydroxide powders were separated from waste WC-Co hard metal with acid-base chemical treatment, and then the impurities were eliminated by centrifuge method. Subsequently, Co_3O_4 powders were prepared by thermal treatment of resulting Co(OH)_2. By adding a certain amount of Li_2CO_3 and LiOHcdotH_2O, the LiCoO_2 was obtained by sintering for 10 h in air at 800°C. The synthesized LiCoO_2 particles were characterized by X-ray diffraction (XRD) and Scanning Electron Microscope (SEM) analysis.

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