- Formation of Phases and Mechanical Properties of YSZ-Based Thermal Barrier Coating Materials Doped with Rare Earth Oxides
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Yong Seok Choi, Gye Won Lee, Sahn Nahm, Yoon suk Oh
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J Powder Mater. 2023;30(5):402-408. Published online October 1, 2023
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DOI: https://doi.org/10.4150/KPMI.2023.30.5.402
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Abstract
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This study focused on improving the phase stability and mechanical properties of yttria-stabilized zirconia (YSZ), commonly utilized in gas turbine engine thermal barrier coatings, by incorporating Gd2O3, Er2O3, and TiO2. The addition of 3-valent rare earth elements to YSZ can reduce thermal conductivity and enhance phase stability while adding the 4-valent element TiO2 can improve phase stability and mechanical properties. Sintered specimens were prepared with hot-press equipment. Phase analysis was conducted with X-ray diffraction (XRD), and mechanical properties were assessed with Vickers hardness equipment. The research results revealed that, except for Z10YGE10T, most compositions predominantly exhibited the t-phase. Increasing the content of 3-valent rare earth oxides resulted in a decrease in the monoclinic phase and an increase in the tetragonal phase. In addition, the t(400) angle decreased while the t(004) angle increased. The addition of 10 mol% of 3-valent rare-earth oxides discarded the t-phase and led to the complete development of the c-phase. Adding 10 mol% TiO2 increased hardness than YSZ.
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