- Synthesis and Photo Catalytic Activity of 10 wt%, 20 wt%Li-TiO2 Composite Powders
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Hyeong-Chul Kim, Jae-Kil Han
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J Korean Powder Metall Inst. 2016;23(1):33-37. Published online February 1, 2016
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DOI: https://doi.org/10.4150/KPMI.2016.23.1.33
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10 wt.% and 20 wt.%Li-TiO2 composite powders are synthesized by a sol-gel method using titanium isopropoxide and Li2CO3 as precursors. The as-received amorphous 10 wt.%Li-TiO2 composite powders crystallize into the anatase-type crystal structure upon calcination at 450°C, which then changes to the rutile phase at 750°C. The asreceived 20 wt%Li-TiO2 composite powders, on the other hand, crystallize into the anatase-type structure. As the calcination temperature increases, the anatase TiO2 phase gets transformed to the LiTiO2 phase. The peaks for the samples obtained after calcination at 900°C mainly exhibit the LiTiO2 and Li2TiO3 phases. For a comparison of the photocatalytic activity, 10 wt.% and 20 wt.% Li-TiO2 composite powders calcined at 450°C, 600°C, and 750°C are used. The 20 wt.%Li-TiO2 composite powders calcined at 600°C show excellent efficiency for the removal of methylorange.
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- Microstructure and Sintering Behavior of Injection Molded Fe Sintered Body Using Rapid Thermal Heating Process
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Ki-Hyun Kim, Jae-Kil Han, Ji-Hun Yu, Chul-Jin Choi, Byong-Taek Lee
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J Korean Powder Metall Inst. 2004;11(6):528-534.
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DOI: https://doi.org/10.4150/KPMI.2004.11.6.528
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Abstract
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- Using the nano Fe powders having 50 nm in diameter, Fe compact bodies were fabricated by injec-tion molding process. The relationship between microstructure and material properties depending on the volume ratio of powder/binder and sintering temperature were characterized by SEM, TEM techniques. In the compact body with the volume percentage ratio of 45(Fe powder) : 55(binder), which was sintered at 700°C, the relative density was about 97%, and the values of volume shrinkage and hardness were about 66.3% and 242.0 Hv, respec-tively. Using the composition of 50(Fe powder) : 50(binder) and sintered at 700°C, the values of relative density, volume shrinkage and hardness of Fe sintered bodies were 73.3%,;47.6% and 152.8 Hv, respectively. They showed brittle fracture mode due to the porous and fine microstructure.
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