- Production of Porous Metallic Glass Granule by Optimizing Chemical Processing
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Song-Yi Kim, Bo-Kyung Guem, Min-Ha Lee, Taek-Soo Kim, Jurgen Eckert, Bum-Sung Kim
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J Korean Powder Metall Inst. 2014;21(4):251-255. Published online August 1, 2014
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DOI: https://doi.org/10.4150/KPMI.2014.21.4.251
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Abstract
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In this study, we optimized dissolution the dissolution conditions of porous amorphous powder to have high specific surface area. Porous metallic glass(MG) granules were fabricated by selective phase dissolution, in which brass is removed from a composite powder consisting of MG and 40 vol.% brass. Dissolution was achieved through various concentrations of H2SO4 and HNO3, with HNO3 proving to have the faster reaction kinetics. Porous powders were analyzed by differential scanning calorimetry to observe crystallization behavior. The Microstructure of milled powder and dissolved powder was analyzed by scanning electron microscope. To check for residual in the dissolved powder after dissolution, energy dispersive X-ray spectroscory and elemental mapping was conducted. It was confirmed that the MG/brass composite powder dissolved in 10% HNO3 produced a porous MG granule with a relatively high specific surface area of 19.60 m2/g. This proved to be the optimum dissolution condition in which both a porous internal granule structure and amorphous phase were maintained. Consequently, porous MG granules were effectively fabricated and applications of such structures can be expanded.
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