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[Korean]
Phase Formation and Physical Properties of SiAlON Ceramics Fabricated by Gas-Pressure Reactive Sintering
Soyul Lee, Jae-Hyeong Choi, Yoonsoo Han, Sung-Min Lee, Seongwon Kim
J Korean Powder Metall Inst. 2017;24(6):431-436.   Published online December 1, 2017
DOI: https://doi.org/10.4150/KPMI.2017.24.6.431
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SiAlON-based ceramics are some of the most typical oxynitride ceramic materials, which can be used as cutting tools for heat-resistant super-alloys (HRSA). SiAlON can be fabricated by using gas-pressure reactive sintering from the raw materials, nitrides and oxides such as Si3N4, AlN, Al2O3, and Yb2O3. In this study, we fabricate Ybm/3Si12-(m+n)Alm+nOnN16-n (m=0.3, n=1.9, 2.3, 2.7) ceramics by using gas-pressure sintering at different sintering temperatures. Then, the densification behavior, phase formation, microstructure, and hardness of the sintered specimens are characterized. We obtain a fully densified specimen with β- SiAlON after gas-pressure sintering at 1820°C for 90 min. under 10 atm N2 pressure. These SiAlON ceramic materials exhibited hardness values of ~92.9 HRA. The potential of these SiAlON ceramics for cutting tool application is also discussed.


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