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Formation of Nano-oxides on Porous Metallic Glass Compacts using Hydrothermal Synthesis
H. J. Park, Y. S. Kim, S. H. Hong, J. T. Kim, J. Y. Cho, W. H. Lee, K. B. Kim
J Korean Powder Metall Inst. 2015;22(4):229-233.   Published online August 1, 2015
DOI: https://doi.org/10.4150/KPMI.2015.22.4.229
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Porous metallic glass compact (PMGC) are developed by electro-discharge sintering (EDS) process of gas atomized Zr41.2Ti13.8Cu12.5Ni10Be22.5 metallic glass powder under of 0.2 kJ generated by a 450 μF capacitor being charged to 0.94 kV. Functional iron-oxides are formed and growth on the surface of PMGCs via hydrothermal synthesis. It is carried out at 150°C for 48hr with distilled water of 100 mL containing Fe ions of 0.18 g/L. Consequently, two types of iron oxides with different morphology which are disc-shaped Fe2O3 and needle-shaped Fe3O4 are successfully formed on the surface of the PMGCs. This finding suggests that PMGC witih hydrothermal technique can be attractive for the practical technology as a new area of structural and functional materials. And they provide a promising road map for using the metallic glasses as a potential functional application.

Citations

Citations to this article as recorded by  
  • Enhanced wear resistivity of a Zr-based bulk metallic glass processed by high-pressure torsion under reciprocating dry conditions
    Soo-Hyun Joo, Dong-Hai Pi, Jing Guo, Hidemi Kato, Sunghak Lee, Hyoung Seop Kim
    Metals and Materials International.2016; 22(3): 383.     CrossRef
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Synthesis and Characterization of SnO2-CoO/carbon-coated CoO Core/shell Nanowire Composites
Yu-Jin Lee, Bon-Ryul Koo, Hyo-Jin Ahn
J Korean Powder Metall Inst. 2014;21(5):360-365.   Published online October 1, 2014
DOI: https://doi.org/10.4150/KPMI.2014.21.5.360
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SnO2-CoO/carbon-coated CoO core/shell nanowire composites were synthesized by using electrospinning and hydrothermal methods. In order to obtain SnO2-CoO/carbon-coated CoO core/shell nanowire composites, SnO2-Co3O4 nanowire composites and SnO2-Co3O4/polygonal Co3O4 core/shell nanowire composites are also synthesized. To demonstrate their structural, chemical bonding, and morphological properties, field-emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy were carried out. These results indicated that the morphologies and structures of the samples were changed from SnO2-Co3O4 nanowires having cylindrical structures to SnO2-Co3O4/Co3O4 core/shell nanowires having polygonal structures after a hydrothermal process. At last, SnO2-CoO/carbon-coated CoO core/shell nanowire composites having irregular and high surface area are formed after carbon coating using a polypyrrole (PPy). Also, there occur phases transformation of cobalt phases from Co3O4 to CoO during carbon coating using a PPy under a argon atmosphere.

Citations

Citations to this article as recorded by  
  • Co-Embedded Graphitic Porous Carbon Nanofibers for Pt-Free Counter Electrode in Dye-Sensitized Solar Cells
    혜란 안, 혜린 강, 효정 선, 지호 한, 효진 안
    Korean Journal of Materials Research.2015; 25(12): 672~677.     CrossRef
  • Synthesis of Perforated Polygonal Cobalt Oxides usinga Carbon Nanofiber Template
    Dong-Yo Sin, Geon-Hyoung An, Hyo-Jin Ahn
    Journal of Korean Powder Metallurgy Institute.2015; 22(5): 350.     CrossRef

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