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High-Temperature Steam Oxidation Behavior of Silicide- or Aluminide- Coated Mo and Nb Refractory Metals
Woojin Lim, Je-Kyun Baek, JaeJoon Kim, Hyun Gil Kim, Ho Jin Ryu
J Powder Mater. 2024;31(6):546-555.   Published online December 31, 2024
DOI: https://doi.org/10.4150/jpm.2024.00381
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Refractory materials, such as molybdenum and niobium, are potential candidates for cladding material due to their high melting temperatures and desirable mechanical properties at higher temperatures than those of zirconium alloys. However, refractory materials have low resistance to oxidation at elevated temperatures. Therefore, this study examined silicide or aluminide surface coatings as protection against rapid oxidation of refractory materials at elevated temperatures for a potential accident-tolerant fuel cladding. Silicide or aluminide layers were formed on refractory metal substrates by using the pack cementation method. The steam oxidation behavior of both coated and uncoated samples was compared by thermogravimetric analysis at 1200°C. The weight changes of the coated samples were greatly reduced than those of uncoated samples. Microstructural analyses demonstrated that the silicide and aluminide layers were oxidized to form a protective surface oxide that prevented rapid oxidation of the refractory substrate at elevated temperatures.
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Oxidation Behaviors and Degradation Properties of Aluminide Coated Stainless Steel at High Temperature
Cheol Hong Hwang, Hyo Min Lee, Jeong Seok Oh, Dong Hyeon Hwang, Yu Seok Hwang, Jong Won Lee, Jeong Mook Choi, Joon Sik Park
J Korean Powder Metall Inst. 2021;28(5):396-402.   Published online October 1, 2021
DOI: https://doi.org/10.4150/KPMI.2021.28.5.396
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Stainless steel, a type of steel used for high-temperature parts, may cause damage when exposed to high temperatures, requiring additional coatings. In particular, the Cr2O3 product layer is unstable at 1000°C and higher temperatures; therefore, it is necessary to improve the oxidation resistance. In this study, an aluminide (Fe2Al5 and FeAl3) coating layer was formed on the surface of STS 630 specimens through Al diffusion coatings from 500°C to 700°C for up to 25 h. Because the coating layers of Fe2Al5 and FeAl3 could not withstand temperatures above 1200°C, an Al2O3 coating layer is deposited on the surface through static oxidation treatment at 500°C for 10 h. To confirm the ablation resistance of the resulting coating layer, dynamic flame exposure tests were conducted at 1350°C for 5–15 min. Excellent oxidation resistance is observed in the coated base material beneath the aluminide layer. The conditions of the flame tests and coating are discussed in terms of microstructural variations.

Citations

Citations to this article as recorded by  
  • Thermal Stability and Degradation Properties of Aluminide Coated and Uncoated Ti-6Al-4V Alloys Exposed to High Temperature Flame
    C. Hwang, J. Park, J. Oh, D. Han, S. Lee, K. Shin, J. Choi, K. P. Shinde, J. S. Park
    Metals and Materials International.2023; 29(7): 1855.     CrossRef

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