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Effect of Polymeric Binders on Green body Properties of WC-Co Cemented Carbides
Young-Soo Lim, Sun-Yong Ahn, Jae-Suk Lim, Yeong-Kyeun Paek, Tai-Joo Chung
J Powder Mater. 2022;29(4):291-296.   Published online August 1, 2022
DOI: https://doi.org/10.4150/KPMI.2022.29.4.291
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The green body of WC-Co cemented carbides containing polymeric binders such as paraffin, polyethylene glycol (PEG), and polyvinyl acetate (PVA) are prepared. The green density of the WC-Co cemented carbides increases with the addition of binders, with the exception of PVA, which is known to be a polar polymeric substance. The green strength of the WC-Co cemented carbides improves with the addition of paraffin and a mixture of PEG400 and PEG4000. In contrast, the green strength of the WC-Co does not increase when PEG400 and PEG4000 is added individually. The compressive strength of the green body increases to 14 MPa, and the machinability of the green body improves when more than 4–6 wt% paraffin and a mixture of PEG400 and PEG4000 is used. Simultaneously, the sintered density of WC-Co is as high as 99% relative density, similar to a low binder addition of 1–2 wt%.

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Microstructural Evolution and Properties in Ti(CN)-Co/Ni Cermet Depending on the Starting Material for Incorporation of WC
Tai-Joo Chung, Sun-Yong Ahn, Seung-Su Ahn, Myung-Soo Shin, Hak-Kyu Kim, Kyung-Bae Kim, Kyung-Sik Oh, Hyuk-Jae Lee
J Korean Powder Metall Inst. 2007;14(2):132-139.
DOI: https://doi.org/10.4150/KPMI.2007.14.2.132
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In the Ti(CN)-Co/Ni cermet, WC is an effective additive for increasing sinterability and mechanical properties such as toughness and hardness. In this work, WC, (WTi)C and (WTi)(CN) were used as the source of WC and their effects were investigated in the respect of microstructural evolution and mechanical properties. Regardless of the kinds of WC sources, the hard phase with dark core and bright rim structure was observed in the Ti(CN)-Co/Ni cermet under the incorporation of relatively small amount of WC. However, hard phases with bright core began to appear and their frequency increased with the increase of all kinds of WC source addition. The ratio of bright core to dark one in the (TiW)(CN)-Co/Ni cermet was greatest under the incorporation of (WTi)C compared at the same equivalent amount of WC. The mechanical properties were improved with the addition of WC irrespective of the kinds of sources, but the addition of (WTi)(CN) was less effective for the increase of fracture toughness.

Citations

Citations to this article as recorded by  
  • Investigation into the microstructure and cutting performance of (Ti,Ta,W)(CN)–Co/Ni cermets
    Se-Woong Oh, Sun-Yong Ahn, Kyung-Sik Oh, Hyukjae Lee, Tai-Joo Chung
    International Journal of Refractory Metals and Hard Materials.2015; 53: 36.     CrossRef

Journal of Powder Materials : Journal of Powder Materials