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[Korean]
Development of Composite-film-based Flexible Energy Harvester using Lead-free BCTZ Piezoelectric Nanomaterials
Gwang Hyeon Kim, Hyeon Jun Park, Bitna Bae, Haksu Jang, Cheol Min Kim, Donghun Lee, Kwi-Il Park
J Powder Mater. 2024;31(1):16-22.   Published online February 28, 2024
DOI: https://doi.org/10.4150/KPMI.2024.31.1.16
  • 590 View
  • 24 Download
  • 7 Citations
AbstractAbstract PDF
Composite-based piezoelectric devices are extensively studied to develop sustainable power supply and selfpowered devices owing to their excellent mechanical durability and output performance. In this study, we design a leadfree piezoelectric nanocomposite utilizing (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 (BCTZ) nanomaterials for realizing highly flexible energy harvesters. To improve the output performance of the devices, we incorporate porous BCTZ nanowires (NWs) into the nanoparticle (NP)-based piezoelectric nanocomposite. BCTZ NPs and NWs are synthesized through the solidstate reaction and sol-gel-based electrospinning, respectively; subsequently, they are dispersed inside a polyimide matrix. The output performance of the energy harvesters is measured using an optimized measurement system during repetitive mechanical deformation by varying the composition of the NPs and NWs. A nanocomposite-based energy harvester with 4:1 weight ratio generates the maximum open-circuit voltage and short-circuit current of 0.83 V and 0.28 A, respectively. In this study, self-powered devices are constructed with enhanced output performance by using piezoelectric energy harvesting for application in flexible and wearable devices.

Citations

Citations to this article as recorded by  
  • Long‐Lasting, Steady and Enhanced Energy Harvesting by Inserting a Conductive Layer into the Piezoelectric Polymer
    HakSu Jang, Gwang Hyeon Kim, Dong Won Jeon, Hyeon Jun Park, BitNa Bae, Nagamalleswara Rao Alluri, Cheol Min Kim, Changyeon Baek, Min‐Ku Lee, Sung Beom Cho, Gyoung‐Ja Lee, Kwi‐Il Park
    Advanced Functional Materials.2025;[Epub]     CrossRef
  • Flexible hybrid thermoelectric films made of bismuth telluride-PEDOT:PSS composites enabled by freezing-thawing process and simple chemical treatment
    Cheol Min Kim, Seoha Kim, Nagamalleswara Rao Alluri, Bitna Bae, Momanyi Amos Okirigiti, Gwang Hyun Kim, Hyeon Jun Park, Haksu Jang, Changyeon Baek, Min-Ku Lee, Gyoung-Ja Lee, Kwi-Il Park
    Materials Today Chemistry.2025; 44: 102532.     CrossRef
  • Dual-controlled piezoelectric composite film with enhanced crystallinity and defect-free via solvent vapor treatment
    HakSu Jang, Hyeon Jun Park, Gwang Hyeon Kim, Cheol Min Kim, Nagamalleswara Rao Alluri, BitNa Bae, HyoMin Jeon, DongHun Lee, Kwi-Il Park
    Nano Energy.2025; 136: 110705.     CrossRef
  • Optimized Process and Mechanical and Electrical Analysis of Polyimide/Pb(Zr,Ti)O3-Based Flexible Piezoelectric Composites
    Junki Lee, Sang-il Yoon, Hyunseung Kim, Chang Kyu Jeong
    Journal of Powder Materials.2025; 32(1): 16.     CrossRef
  • Flexible Thermoelectric Energy Harvester with Stacked Structure of Thermoelectric Composite Films Made of PVDF and Bi2Te3-Based Particles
    Da Eun Shin, Nagamalleswara Rao Alluri, Kwi-Il Park
    ACS Applied Energy Materials.2024; 7(19): 8288.     CrossRef
  • Enhanced energy harvesting of fibrous composite membranes via plasma-piezopolymer interaction
    Hyeon Jun Park, Bitna Bae, HakSu Jang, Dong Yeol Hyeon, Dong Hun Lee, Gwang Hyun Kim, Cheol Min Kim, Nagamalleswara Rao Alluri, Changyeon Baek, Min-Ku Lee, Gyoung-Ja Lee, Kwi-Il Park
    Nano Energy.2024; 131: 110299.     CrossRef
  • CoFe2O4-BaTiO3 core-shell-embedded flexible polymer composite as an efficient magnetoelectric energy harvester
    Bitna Bae, Nagamalleswara Rao Alluri, Cheol Min Kim, Jungho Ryu, Gwang Hyeon Kim, Hyeon Jun Park, Changyeon Baek, Min-Ku Lee, Gyoung-Ja Lee, Geon-Tae Hwang, Kwi-Il Park
    Materials Today Physics.2024; 48: 101567.     CrossRef
Article
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[Korean]
Effects of the Mixing Method and Sintering Temperature on the Characteristics of PZNN-PZT Piezoelectric Ceramic Materials
So Won Kim, Yong Jeong Jeong, Hee Chul Lee
J Korean Powder Metall Inst. 2018;25(6):487-493.   Published online December 1, 2018
DOI: https://doi.org/10.4150/KPMI.2018.25.6.487
  • 323 View
  • 2 Download
  • 5 Citations
AbstractAbstract PDF

The impact of different mixing methods and sintering temperatures on the microstructure and piezoelectric properties of PZNN-PZT ceramics is investigated. To improve the sinterability and piezoelectric properties of these ceramics, the composition of 0.13Pb((Zn0.8Ni0.2)1/3Nb2/3)O3-0.87Pb(Zr0.5Ti0.5)O3 (PZNN-PZT) containing a Pb-based relaxor component is selected. Two methods are used to create the powder for the PZNN-PZT ceramics. The first involves blending all source powders at once, followed by calcination. The second involves the preferential creation of columbite as a precursor, by reacting NiO with Nb2O5 powder. Subsequently, PZNN-PZT powder can be prepared by mixing the columbite powder, PbO, and other components, followed by an additional calcination step. All the PZNNPZT powder samples in this study show a nearly-pure perovskite phase. High-density PZNN-PZT ceramics can be fabricated using powders prepared by a two-step calcination process, with the addition of 0.3 wt% MnO2 at even relatively low sintering temperatures from 800°C to 1000°C. The grain size of the ceramics at sintering temperatures above 900°C is increased to approximately 3 μm. The optimized PZNN-PZT piezoelectric ceramics show a piezoelectric constant (d33) of 360 pC/N, an electromechanical coupling factor (kp) of 0.61, and a quality factor (Qm) of 275.

Citations

Citations to this article as recorded by  
  • An Analysis of Edge Chipping in LiTaO3 Wafer Grinding Using a Scratch Test and FEA Simulation
    Haeseong Hwang, Seungho Han, Hyunseop Lee
    Lubricants.2023; 11(7): 297.     CrossRef
  • A generalized rule for phase transition generated by additives in piezoelectric ceramics
    Jae-Min Cha, Young-Kook Moon, Jung-hwan Kim, Hyun-Ae Cha, Jong-Jin Choi, Byung-Dong Hahn, Seog-Young Yoon, Cheol-Woo Ahn
    Materials Today Communications.2023; 37: 107290.     CrossRef
  • Low-Temperature Sintering Properties of Bi2O3 Doped PZT-5H Piezoelectric Ceramics
    Wanzi Mao, Qing Xu, Duanping Huang, Huajun Sun, Feng Zhang, Xiaobin Xie
    Journal of Electronic Materials.2023; 52(5): 3334.     CrossRef
  • Effect of LiBiO2 on low-temperature sintering of PZT-PZNN ceramics
    Sung Cheul Hong, Shi Yeon Kim, Dong-Hun Yeo, Hyo-Soon Shin, Zee Hoon Park, Sahn Nahm
    Journal of the Korean Ceramic Society.2022; 59(5): 638.     CrossRef
  • Two-Stage De-binding for Cu Electrode Application to PZT-PZNN Multilayer Actuator
    Sung Cheul Hong, Zeehoon Park, Dong-Hun Yeo, Hyo-Soon Shin, Sahn Nahm
    Transactions on Electrical and Electronic Materials.2022; 23(4): 348.     CrossRef
Research Article
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[English]
Development of Powder Injection Molding Process for a Piezoelectric PAN-PZT Ceramics
Jun Sae Han, Dong Yong Park, Dongguo Lin, Kwang Hyun Chung, Ravi Bollina, Seong Jin Park
J Korean Powder Metall Inst. 2016;23(2):112-119.   Published online April 1, 2016
DOI: https://doi.org/10.4150/KPMI.2016.23.2.112
  • 321 View
  • 5 Download
  • 4 Citations
AbstractAbstract PDF

A powder injection molding process is developed and optimized for piezoelectric PAN-PZT ceramics. Torque rheometer experiments are conducted to determine the optimal solids loading, and the rheological property of the feedstock is evaluated using a capillary rheometer. Appropriate debinding conditions are chosen using a thermal gravity analyzer, and the debound specimens are sintered using sintering conditions determined in a preliminary investigation. Piezoelectric performance measures, including the piezoelectric charge constant and dielectric constant, are measured to verify the developed process. The average values of the measured piezoelectric charge constant and dielectric constant are 455 pC/N and 1904, respectively. Powder injection molded piezoelectric ceramics produced by the optimized process show adequate piezoelectric performance compared to press-sintered piezoelectric ceramics.

Citations

Citations to this article as recorded by  
  • Study on Rheological Behavior and Mechanical Properties of PMN–PZT Ceramic Feedstock
    Jae Man Park, Jun Sae Han, Joo Won Oh, Seong Jin Park
    Metals and Materials International.2021; 27(5): 1069.     CrossRef
  • Investigation of stainless steel 316L/zirconia joint part fabricated by powder injection molding
    Chang Woo Gal, Sang Soo Han, Jun Sae Han, Dongguo Lin, Seong Jin Park
    International Journal of Applied Ceramic Technology.2019; 16(1): 315.     CrossRef
  • Fabrication of pressureless sintered Si3N4 ceramic balls by powder injection molding
    Chang Woo Gal, Gi Woung Song, Woon Hyung Baek, Hyung Kyu Kim, Dae Keun Lee, Ki Wook Lim, Seong Jin Park
    Ceramics International.2019; 45(5): 6418.     CrossRef
  • Experimental analysis for fabrication of high-aspect-ratio piezoelectric ceramic structure by micro-powder injection molding process
    Jun Sae Han, Chang Woo Gal, Jae Man Park, Jong Hyun Kim, Seong Jin Park
    Materials Research Express.2018; 5(4): 046303.     CrossRef

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