Spherical monosized pure aluminum (Al) particles are successfully fabricated by the pulsated orifice ejection method (POEM). The surface reaction between Al and the graphite crucible is investigated by analysing the microstructure and chemical composition of the materials. No significant chemical reaction occurs between Al and the graphite owing to the crystalline Al oxide (γ-Al₂O₃) layer generated in the initial state. The γ-Al₂O₃ layer is clearly observed in all regions between the Al particles and graphite via transmission electron microscopy and confirmed by the selected area diffraction pattern. The morphology of the γ-Al₂O₃ layer perfectly follows the surface morphology of the graphite crucible, which showed nanoscale roughness. This implies that molten Al could not directly contact graphite even though the surface of the crucible became rough to some extent. However, this passivation phenomenon allowed the successful fabrication of monosized pure Al particles. Therefore, POEM is a useful process at least to manufacture monosized pure Al particles.

Grain-growth behavior in the 95Na_1/2Bi_1/2TiO₃-5BaTiO₃ (mole fraction, NBT-5BT) system has been investigated with the addition of Na₂CO₃. When Na₂CO₃ is added to NBT-5BT, the growth rate is higher than desired and grains are already impinging each other during the initial stage of sintering. The grain size decreases as the sintering temperature increases. With the addition of Na₂CO₃, a liquid phase infiltrates the interfaces between grains during sintering. The interface structure can be changed to be more faceted and the interface migration rate can increase due to fast material transport through the liquid phase. As the sintering temperature increases, the impingement of abnormal grains increases because the number of abnormal grains increases. Therefore, the average grain size of abnormal grains can be decreased as the temperature increases. The phenomenon can provide evidence that grain coarsening in NBT-5BT with addition of Na₂CO₃ is governed by the growth of facet planes, which would occur via mixed control.

Citations

Citations to this article as recorded by  

• Growth of single crystals in the (Na1/2Bi1/2)TiO3–(Sr1–xCax)TiO3 system by solid state crystal growth
  Phan Gia Le, Huyen Tran Tran, Jong-Sook Lee, John G. Fisher, Hwang-Pill Kim, Wook Jo, Won-Jin Moon
  Journal of Advanced Ceramics.2021; 10(5): 973.     CrossRef
• Sintering Behavior of M-type Sr-Hexaferrite by MnCO₃ Addition
  MinSeok Jeong, Changjae You, Jung Young Cho, Kyoung-Seok Moon
  Journal of Korean Powder Metallurgy Institute.2020; 27(2): 126.     CrossRef

The objective of this study is to reveal the sintering mechanism of mixed Ti-6Al-4V powders considering the densification and the homogenization between Ti and Al/V particles. It is found that the addition of master alloy particles into Ti enhances densification by the migration of Al into the Ti matrix prior to the self-diffusion of Ti. However, as Ti particles become coarser, sintering of the powders appears to be retarded due to slower inter-diffusion of the particles due to the reduced surface energies of Ti. Such phenomena are confirmed by a series of dilatometry tests and microstructural analyses in respect to the sintering temperature. Furthermore, the results are also consistent with the predicted activation energies for sintering. The energies are found to have decreased from 299.35 to 135.48 kJ·mol^-1 by adding the Al/V particles because the activation energy for the diffusion of Al in α-Ti (77 kJ·mol^-1) is much lower than that of the self-diffusion of α-Ti. The coarser Ti powders increase the energies from 135.48 to 181.16 kJ·mol^-1 because the specific surface areas of Ti decrease.

Boron nitride nanotubes (BNNTs) are receiving great attention because of their unusual material properties, such as high thermal conductivity, mechanical strength, and electrical resistance. However, high-throughput and highefficiency synthesis of BNNTs has been hindered due to the high boiling point of boron (~ 4000°C) and weak interaction between boron and nitrogen. Although, hydrogen-catalyzed plasma synthesis has shown potential for scalable synthesis of BNNTs, the direct use of H₂ gas as a precursor material is not strongly recommended, as it is extremely flammable. In the present study, BNNTs have been synthesized using radio-frequency inductively coupled thermal plasma (RF-ITP) catalyzed by solid-state ammonium chloride (NH₄Cl), a safe catalyst materials for BNNT synthesis. Similar to BNNTs synthesized from h-BN (hexagonal boron nitride) + H₂, successful fabrication of BNNTs synthesized from h-BN+NH₄Cl is confirmed by their sheet-like properties, FE-SEM images, and XRD analysis. In addition, improved dispersion properties in aqueous solution are found in BNNTs synthesized from h-BN +NH₄Cl.

In the present study, we investigate the effects of milling time and the addition of a process control agent (PCA) on the austenite stability of a nanocrystalline Fe-7%Mn alloy by XRD analysis and micrograph observation. Nanocrystalline Fe-7%Mn alloys samples are successfully fabricated by spark plasma sintering. The crystallite size of ball-milled powder and the volume fraction of austenite in the sintered sample are calculated using XRD analysis. Changes in the shape and structure of alloyed powder according to milling conditions are observed through FE-SEM. It is found that the crystallite size is reduced with increasing milling time and amount of PCA addition due to the variation in the balance between the cold-welding and fracturing processes. As a result, the austenite stability increased, resulting in an exceptionally high volume fraction of austenite retained at room temperature.

Citations

Citations to this article as recorded by  

• Effect of Cooling Rate on Microstructure and Hardness during Solution Treatment and Aging Process of Ti-6Al-4V Alloy for Aerospace Components
  Seongji Seo, Hojoon Choi, Geeyoung Lee, Kee-Ahn Lee, Jeongho Han, Minsu Jung
  Journal of Materials Engineering and Performance.2021; 30(5): 3406.     CrossRef
• Development of Fe-Mn-based Hybrid Materials Containing Nano-scale Oxides by a Powder Metallurgical Route
  Jonggyu Jeon, Jungjoon Kim, Hyunjoo Choi
  Journal of Korean Powder Metallurgy Institute.2020; 27(3): 203.     CrossRef
• Austenite Stability of Sintered Fe-based Alloy
  Seunggyu Choi, Namhyuk Seo, Junhyub Jun, Seung Bae Son, Seok-Jae Lee
  Journal of Korean Powder Metallurgy Institute.2020; 27(5): 414.     CrossRef
• Austenite Stability of Nanocrystalline FeMnNiC Alloy
  Seung-Jin Oh, Junhyub Jeon, In-Jin Shon, Seok-Jae Lee
  Journal of Korean Powder Metallurgy Institute.2019; 26(5): 389.     CrossRef

Core/shell CdSe/ZnS quantum dots (QDs) are synthesized by a microfluidic reactor-assisted continuous reactor system. Photoluminescence and absorbance of synthesized CdSe/ZnS core/shell QDs are investigated by fluorescence spectrophotometry and online UV-Vis spectrometry. Three reaction conditions, namely; the shell coating reaction temperature, the shell coating reaction time, and the ZnS/CdSe precursor volume ratio, are combined in the synthesis process. The quantum yield of the synthesized CdSe QDs is determined for each condition. CdSe/ZnS QDs with a higher quantum yield are obtained compared to the discontinuous microfluidic reactor synthesis system. The maximum quantum efficiency is 98.3% when the reaction temperature, reaction time, and ZnS/CdSe ratio are 270°C, 10 s, and 0.05, respectively. Obtained results indicate that a continuous synthesis of the Core/shell CdSe/ZnS QDs with a high quantum efficiency could be achieved by isolating the reaction from the external environment.

In this study, two types of SKD61 tool-steel samples are built by a selective laser melting (SLM) process using the different laser scan speeds. The characteristics of two kinds of SKD61 tool-steel powders used in the SLM process are evaluated. Commercial SKD61 tool-steel power has a flowability of 16.68 sec/50 g and its Hausner ratio is calculated to be 1.25 by apparent and tapped density. Also, the fabricated SKD61 tool steel powder fabricated by a gas atomization process has a flowability of 21.3 sec/50 g and its Hausner ratio is calculated to be 1.18. Therefore, we confirmed that the two powders used in this study have excellent flowability. Samples are fabricated to measure mechanical properties. The highest densities of the SKD61 tool-steel samples, fabricated under the same conditions, are 7.734 g/cm³ (using commercial SKD61 powder) and 7.652 g/cm³ (using fabricated SKD61 powder), measured with Archimedes method. Hardness is measured by Rockwell hardness testing equipment 5 times and the highest hardnesses of the samples are 54.56 HRC (commercial powder) and 52.62 HRC (fabricated powder). Also, the measured tensile strengths are approximately 1,721 MPa (commercial SKD61 powder) and 1,552 MPa (fabricated SKD61 powder), respectively.

Citations

Citations to this article as recorded by  

• Microstructural effects on the tensile and fracture behavior of selective laser melted H13 tool steel under varying conditions
  Jungsub Lee, Jungho Choe, Junhyeok Park, Ji-Hun Yu, Sangshik Kim, Im Doo Jung, Hyokyung Sung
  Materials Characterization.2019; 155: 109817.     CrossRef

Al₂O₃-SiC ceramic composites are produced using pressureless sintering, and their plasma resistance, electrical resistance, and mechanical properties are evaluated to confirm their applicability as electrostatic-discharge-safe components for semiconductor devices. Through the addition of Mg and Y nitrate sintering aids, it is confirmed that even if SiC content exceeded 10%, complete densification is possible by pressureless sintering. By the uniform distribution of SiC, the total grain growth is suppressed to about 1 μm; thus an Al₂O₃-SiC sintered body with a high strength over 600 MPa is obtained. The optimum amount of SiC to satisfy all the desired properties of electrostaticdischarge-safe ceramic components is obtained by finding the correlation between the plasma resistance and the electrical resistivity as a function of SiC amount.

In this study, the compound Li₃BO₃ (LBO) is intended to be prepared by a polymeric complex method as a sintering aid for the densification of Li₇La₃Zr₂O₁₂ (LLZ) solid electrolyte. A polymeric precursor containing Li and B is heat-treated in an air atmosphere at a temperature range between 600°C and 800°C. Instead of LBO, the compound Li_2+xC_1-xB_xO₃ (LCBO) is unexpectedly synthesized after a heat-treatment of 700°C. The effect of LCBO addition on sintering behavior and ion conductivity of LLZ is studied. It is found that the LCBO compound could lead to significant improvements in the densification and ionic conductivity of LLZ compared to pure LLZ. After sintering at 1100°C, the density of the LLZ-12wt%LBO composite is 3.72 g/cm³, with a high Li-ion conductivity of 1.18 × 10⁻⁴ Scm^-1 at 28°C, while the pure LLZ specimen had a densify of 2.98 g/cm³ and Li-ion conductivity of 5.98 × 10⁻⁶ Scm^-1.

Citations

Citations to this article as recorded by  

• Characterization of Li1.5Al0.5Ge1.5(PO4)3 Solid Electrolyte with an Added Sintering Aid
  Hyun-Joon Lee, Liyu-Liu, Won-Jong Jeong, Seoung-Ki Lee, Bong-Ki Ryu
  Electronic Materials Letters.2023; 19(1): 55.     CrossRef

Multi-walled carbon nanotube (MWCNT)–copper (Cu) composites are successfully fabricated by a combination of a binder-free wet mixing and spark plasma sintering (SPS) process. The SPS is performed under various conditions to investigate optimized processing conditions for minimizing the structural defects of CNTs and densifying the MWCNT–Cu composites. The electrical conductivities of MWCNT–Cu composites are slightly increased for compositions containing up to 1 vol.% CNT and remain above the value for sintered Cu up to 2 vol.% CNT. Uniformly dispersed CNTs in the Cu matrix with clean interfaces between the treated MWCNT and Cu leading to effective electrical transfer from the treated MWCNT to the Cu is believed to be the origin of the improved electrical conductivity of the treated MWCNT–Cu composites. The results indicate the possibility of exploiting CNTs as a contributing reinforcement phase for improving the electrical conductivity and mechanical properties in the Cu matrix composites.

Citations

Citations to this article as recorded by  

• Proposing Machine Learning Models Suitable for Predicting Open Data Utilization
  Junyoung Jeong, Keuntae Cho
  Sustainability.2024; 16(14): 5880.     CrossRef

Rare earth elements (REEs) are considered to be vital to modern industry due to their important roles in applications such as permanent magnets, automobile production, displays, and many more. The imbalance between demand and supply of REEs can be solved by recycling processes. Regarding the needs of industry and society, the International Organization for Standardization, Technical Committee 298 (ISO/TC298) Rare Earths has been recently launched for developing international standards on rare earth elements. In accordance with the suggestion of its constituents, it is tentatively working to develop the appropriate standards under five working groups (WG) on terms and definitions (WG1), element recycling (WG2), environmental stewardship (WG3), packaging, labelling, marking, transport, and storage (WG4), and testing analysis (WG5). The scope and structure of ISO/TC298 on the topic of rare earths is discussed in this document.

Citations

Citations to this article as recorded by  

• Synthesis and magnetic properties of Sm2Co17 particles using salt-assisted spray pyrolysis and a reduction-diffusion process
  Tae-Yeon Hwang, Jimin Lee, Min Kyu Kang, Gyutae Lee, Jongryoul Kim, Yong-Ho Choa
  Applied Surface Science.2019; 475: 986.     CrossRef
• Worker Safety in the Rare Earth Elements Recycling Process From the Review of Toxicity and Issues
  Seo-Ho Shin, Hyun-Ock Kim, Kyung-Taek Rim
  Safety and Health at Work.2019; 10(4): 409.     CrossRef

Colloidally synthesized luminescent nanocrystals (NCs) have attracted tremendous attention due to their unique nanoscale optical and electronic properties. The emission properties of these NCs can be precisely tuned by controlling their size, shape, and composition as well as by introducing appropriate dopant impurities. Nowadays, these NCs are actively utilized for various applications such as optoelectronic devices including light emitting diodes (LEDs), lasers, and solar cells, and bio-medical applications such as imaging agents and bio-sensors. In this review, we classify luminescent nanomaterials into quantum dots (QDs), upconversion nanoparticles (UCNPs), and perovskite NCs and present their intrinsic emission mechanism. Furthermore, the recently emerging issues of efficiency, toxicity, and durability in these materials are discussed for better understanding of industry demands. As well, the future outlook will be offered for researchers to guide the direction of future research.

Citations

Citations to this article as recorded by  

• A Structural Relationship between University Dance Students’ Emotional Regulation, Emotion Response, and Engagement in Classes
  Jinhee Gong
  The Journal of Korean Institute of Information Technology.2020; 18(4): 121.     CrossRef