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Trends in Materials Modeling and Computation for Metal Additive Manufacturing
Seoyeon Jeon, Hyunjoo Choi
J Powder Mater. 2024;31(3):213-219.   Published online June 27, 2024
DOI: https://doi.org/10.4150/jpm.2024.00150
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AbstractAbstract PDF
Additive Manufacturing (AM) is a process that fabricates products by manufacturing materials according to a three-dimensional model. It has recently gained attention due to its environmental advantages, including reduced energy consumption and high material utilization rates. However, controlling defects such as melting issues and residual stress, which can occur during metal additive manufacturing, poses a challenge. The trial-and-error verification of these defects is both time-consuming and costly. Consequently, efforts have been made to develop phenomenological models that understand the influence of process variables on defects, and mechanical/electrical/thermal properties of geometrically complex products. This paper introduces modeling techniques that can simulate the powder additive manufacturing process. The focus is on representative metal additive manufacturing processes such as Powder Bed Fusion (PBF), Direct Energy Deposition (DED), and Binder Jetting (BJ) method. To calculate thermal-stress history and the resulting deformations, modeling techniques based on Finite Element Method (FEM) are generally utilized. For simulating the movements and packing behavior of powders during powder classification, modeling techniques based on Discrete Element Method (DEM) are employed. Additionally, to simulate sintering and microstructural changes, techniques such as Monte Carlo (MC), Molecular Dynamics (MD), and Phase Field Modeling (PFM) are predominantly used.
Research Articles
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Investigation of the Thermal-to-Electrical Properties of Transition Metal-Sb Alloys Synthesized for Thermoelectric Applications
Jong Min Park, Seungki Jo, Sooho Jung, Jinhee Bae, Linh Ba Vu, Kwi-Il Park, Kyung Tae Kim
J Powder Mater. 2024;31(3):236-242.   Published online June 27, 2024
DOI: https://doi.org/10.4150/jpm.2024.00031
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The development of thermoelectric (TE) materials to replace Bi2Te3 alloys is emerging as a hot issue with the potential for wider practical applications. In particular, layered Zintl-phase materials, which can appropriately control carrier and phonon transport behaviors, are being considered as promising candidates. However, limited data have been reported on the thermoelectric properties of metal-Sb materials that can be transformed into layered materials through the insertion of cations. In this study, we synthesized FeSb and MnSb, which are used as base materials for advanced thermoelectric materials. They were confirmed as single-phase materials by analyzing X-ray diffraction patterns. Based on electrical conductivity, the Seebeck coefficient, and thermal conductivity of both materials characterized as a function of temperature, the zT values of MnSb and FeSb were calculated to be 0.00119 and 0.00026, respectively. These properties provide a fundamental data for developing layered Zintl-phase materials with alkali/alkaline earth metal insertions.
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Bandgap Tuning and Quenching Effects of In(Zn)P@ZnSe@ZnS Quantum Dots
Sang Yeon Lee, Su Hyun Park, Gyungsu Byun, Chang-Yeoul Kim
J Powder Mater. 2024;31(3):226-235.   Published online June 27, 2024
DOI: https://doi.org/10.4150/jpm.2024.00003
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AbstractAbstract PDF
InP quantum dot (QDs) have attracted researchers’ interest due to their applicability in quantum dot light-emitting displays (QLED) or biomarkers for detecting cancers or viruses. The surface or interface control of InP QD core/shell has substantially increased quantum efficiency, with a quantum yield of 100% reached by introducing HF to inhibit oxide generation. In this study, we focused on the control of bandgap energy of quantum dots by changing the Zn/(In+Zn) ratio in the In(Zn)P core. Zinc incorporation can change the photoluminescent light colors of green, yellow, orange, and red. Diluting a solution of as-synthesized QDs by more than 100 times did not show any quenching effects by the Förster resonance energy transfer phenomenon between neighboring QDs.
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The Effect of TiO2 Addition on Low-temperature Sintering Behaviors in a SnO2-CoO-CuO System
Jae-Sang Lee, Kyung-Sik Oh, Yeong-Kyeun Paek
J Powder Mater. 2024;31(2):146-151.   Published online April 30, 2024
DOI: https://doi.org/10.4150/jpm.2024.00024
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AbstractAbstract PDF
Pure SnO2 has proven very difficult to densify. This poor densification can be useful for the fabrication of SnO2 with a porous microstructure, which is used in electronic devices such as gas sensors. Most electronic devices based on SnO2 have a porous microstructure, with a porosity of > 40%. In pure SnO2, a high sintering temperature of approximately 1300C is required to obtain > 40% porosity. In an attempt to reduce the required sintering temperature, the present study investigated the low-temperature sinterability of a current system. With the addition of TiO2, the compositions of the samples were Sn1-xTixO2-CoO(0.3wt%)-CuO(2wt%) in the range of x ≤ 0.04. Compared to the samples without added TiO2, densification was shown to be improved when the samples were sintered at 950C. The dominant mass transport mechanism appears to be grain-boundary diffusion during heat treatment at 950C.
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Inorganic Compound and Cycloserine Composite Particles for Improved Stability
Dongwon Kim, Heeseo Kim, Hongjun Yoon, Hyuk Jun Cho, Sung Giu Jin
J Powder Mater. 2024;31(2):126-131.   Published online April 30, 2024
DOI: https://doi.org/10.4150/jpm.2024.00002
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The aim of this study was to improve the chemical stability of cycloserine containing organic and inorganic compounds. Composite particles were manufactured with a 1:1 weight ratio of organic/inorganic compounds and cycloserine. The influence of organic/inorganic compounds on the stability of cycloserine was investigated under accelerated stress conditions at 60°C/75% RH for 24 hours. In addition, the properties of the composite particles were evaluated using differential scanning calorimetry (DSC), scanning electron microscopy (SEM), and the dissolution of the drug was assessed by preparing it as a hard capsule. Among the organic and inorganic compounds investigated, calcium hydroxide most improved the stability of cycloserine under accelerated stress conditions (53.3 ± 2.2% vs 1.7 ± 0.2%). DSC results confirmed the compatibility between calcium hydroxide and the cycloserine, and SEM results confirmed that it was evenly distributed around the cycloserine. Calcium hydroxide also showed more than 90% cycloserine dissolution within 15 minutes. Therefore, the calcium hydroxide and cycloserine composite particles may be candidates for cycloserine oral pharmaceuticals with enhanced drug stability.
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Fabrication of Bi2Te2.5Se0.5 by Combining Oxide-reduction and Compressive-forming Process and Its Thermoelectric Properties
Young Soo Lim, Gil-Geun Lee
J Powder Mater. 2024;31(1):50-56.   Published online February 28, 2024
DOI: https://doi.org/10.4150/KPMI.2024.31.1.50
  • 266 View
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Fabrication of Ti-Mo Core-shell Powder and Sintering Properties for Application as a Sputtering Target
Won Hee Lee, Chun Woong Park, Heeyeon Kim, Yuncheol Ha, Jongmin Byun, Young Do Kim
J Powder Mater. 2024;31(1):43-49.   Published online February 28, 2024
DOI: https://doi.org/10.4150/KPMI.2024.31.1.43
  • 319 View
  • 14 Download
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Effect of Abnormal Grain Growth on Ionic Conductivity in LATP
Hyungik Choi, Yoonsoo Han
J Powder Mater. 2024;31(1):23-29.   Published online February 28, 2024
DOI: https://doi.org/10.4150/KPMI.2024.31.1.23
  • 365 View
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Review Paper
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Research Trends in Electromagnetic Shielding using MXene-based Composite Materials
Siyeon Kim, Jongmin Byun
J Powder Mater. 2024;31(1):57-76.   Published online February 28, 2024
DOI: https://doi.org/10.4150/KPMI.2024.31.1.57
  • 789 View
  • 34 Download
AbstractAbstract PDF

Recent advancements in electronic devices and wireless communication technologies, particularly the rise of 5G, have raised concerns about the escalating electromagnetic pollution and its potential adverse impacts on human health and electronics. As a result, the demand for effective electromagnetic interference (EMI) shielding materials has grown significantly. Traditional materials face limitations in providing optimal solutions owing to inadequacy and low performance due to small thickness. MXene-based composite materials have emerged as promising candidates in this context owing to their exceptional electrical properties, high conductivity, and superior EMI shielding efficiency across a broad frequency range. This review examines the recent developments and advantages of MXene-based composite materials in EMI shielding applications, emphasizing their potential to address the challenges posed by electromagnetic pollution and to foster advancements in modern electronics systems and vital technologies.

Articles
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Preparation and Evaluation of Ketoconazole-loaded Solid-SNEDDS (Self-Nanoemulsifying Drug Delivery System) using Various Solidification Carriers
Da Young Song, Kyeong Soo Kim
J Powder Mater. 2023;30(6):493-501.   Published online December 1, 2023
DOI: https://doi.org/10.4150/KPMI.2023.30.6.493
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AbstractAbstract PDF

This study aimed to develop a solid self-nanoemulsifying drug delivery system (solid-SNEDDS) to enhance the formulation of ketoconazole (KTZ), a BCS Class II drug with poor solubility. Ketoconazole, which is insoluble above pH 3, requires solubilization for effective delivery. This SNEDDS comprises oil, surfactant, and co-surfactant, which spontaneously emulsify in the gastrointestinal tract environment to form nanoemulsions with droplet sizes less than 100 nm. The optimal SNE-vehicle composition of oleic acid, TPGS, and PEG 400 at a 10:80:10 weight ratio was determined based on the smallest droplet size achieved. This composition was used to prepare liquid SNEDDS containing ketoconazole. The droplet size and polydispersity index (PDI) of the resulting liquid SNEDDS were analyzed. Subsequently, solid-SNEDDS was fabricated using a spray-drying method with solidifying carriers such as silicon dioxide, crospovidone, and magnesium alumetasilicate. The physicochemical properties of the solid-SNEDDS were characterized by scanning electron microscopy and powder X-ray diffraction, and its solubility, droplet size, and PDI were evaluated. In particular, the solid-SNEDDS containing ketoconazole and crospovidone in a 2:1 weight ratio exhibited significantly enhanced solubility, highlighting its potential for improved medication adherence and dissolution rates.

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Combinatorial Experiment for Al-6061 and Al-12Si alloy Based on Directed Energy Deposition (DED) Process
Seoyeon Jeon, Suwon Park, Yongwook Song, Jiwon Park, Hyunyoung Park, Boram Lee, Hyunjoo Choi
J Powder Mater. 2023;30(6):463-469.   Published online December 1, 2023
DOI: https://doi.org/10.4150/KPMI.2023.30.6.463
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  • 1 Citations
AbstractAbstract PDF

Aluminum alloys, known for their high strength-to-weight ratios and impressive electrical and thermal conductivities, are extensively used in numerous engineering sectors, such as aerospace, automotive, and construction. Recently, significant efforts have been made to develop novel aluminum alloys specifically tailored for additive manufacturing. These new alloys aim to provide an optimal balance between mechanical properties and thermal/ electrical conductivities. In this study, nine combinatorial samples with various alloy compositions were fabricated using direct energy deposition (DED) additive manufacturing by adjusting the feeding speeds of Al6061 alloy and Al-12Si alloy powders. The effects of the alloying elements on the microstructure, electrical conductivity, and hardness were investigated. Generally, as the Si and Cu contents decreased, electrical conductivity increased and hardness decreased, exhibiting trade-off characteristics. However, electrical conductivity and hardness showed an optimal combination when the Si content was adjusted to below 4.5 wt%, which can sufficiently suppress the grain boundary segregation of the α- Si precipitates, and the Cu content was controlled to induce the formation of Al2Cu precipitates.

Citations

Citations to this article as recorded by  
  • Trends in Materials Modeling and Computation for Metal Additive Manufacturing
    Seoyeon Jeon, Hyunjoo Choi
    journal of Korean Powder Metallurgy Institute.2024; 31(3): 213.     CrossRef
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Tribological Behavior Analysis of WC-Ni-Cr + Cr3C2 and WC-Ni-Cr + YSZ Coatings Sprayed by HVOF
Tae-Jun Park, Gye-Won Lee, Yoon-Suk Oh
J Powder Mater. 2023;30(5):415-423.   Published online October 1, 2023
DOI: https://doi.org/10.4150/KPMI.2023.30.5.415
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AbstractAbstract PDF

With the increasing attention to environmental pollution caused by particulate matter globally, the automotive industry has also become increasingly interested in particulate matter, especially particulate matter generated by automobile brake systems. Here, we designed a coating composition and analyzed its mechanical properties to reduce particulate matter generated by brake systems during braking of vehicles. We designed a composition to check the mechanical properties change by adding Cr3C2 and YSZ to the WC-Ni-Cr composite composition. Based on the designed composition, coating samples were manufactured, and the coating properties were analyzed by Vickers hardness and ball-on-disk tests. As a result of the experiments, we found that the hardness and friction coefficient of the coating increased as the amount of Cr3C2 added decreased. Furthermore, we found that the hardness of the coating layer decreased when YSZ was added at 20vol%, but the friction coefficient was higher than the composition with Cr3C2 addition.

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Phase Formation and Mechanical Property of YSZ‒30 vol.% WC Composite Ceramics Fabricated by Hot Pressing
Jin-Kwon Kim, Jae-Hyeong Choi, Nahm Sahn, Sung-Soo Ryu, Seongwon Kim
J Powder Mater. 2023;30(5):409-414.   Published online October 1, 2023
DOI: https://doi.org/10.4150/KPMI.2023.30.5.409
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AbstractAbstract PDF

YSZ (Y2O3-stabilized zirconia)-based ceramics have excellent mechanical properties, such as high strength and wear resistance. In the application, YSZ is utilized in the bead mill, a fine-grinding process. YSZ-based parts, such as the rotor and pin, can be easily damaged by continuous application with high rpm in the bead mill process. In that case, adding WC particles improves the tribological and mechanical properties. YSZ-30 vol.% WC composite ceramics are manufactured via hot pressing under different pressures (10/30/60 MPa). The hot-pressed composite ceramics measure the physical properties, such as porosity and bulk density values. In addition, the phase formation of these composite ceramics is analyzed and discussed with those of physical properties. For the increased applied pressure of hot pressing, the tetragonality of YSZ and the crystallinity of WC are enhanced. The mechanical properties indicate an improved tendency with the increase in the applied pressure of hot pressing.

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Synthesis of Carbon Coated Nickel Cobalt Sulfide Yolk-shell Microsphere and Their Application as Anode Materials for Sodium Ion Batteries
Hyo Yeong Seo, Gi Dae Park
J Powder Mater. 2023;30(5):387-393.   Published online October 1, 2023
DOI: https://doi.org/10.4150/KPMI.2023.30.5.387
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AbstractAbstract PDF

Transition metal chalcogenides are promising cathode materials for next-generation battery systems, particularly sodium-ion batteries. Ni3Co6S8-pitch-derived carbon composite microspheres with a yolk-shell structure (Ni3Co6S8@C-YS) were synthesized through a three-step process: spray pyrolysis, pitch coating, and post-heat treatment process. Ni3Co6S8@C-YS exhibited an impressive reversible capacity of 525.2 mA h g-1 at a current density of 0.5 A g-1 over 50 cycles when employed as an anode material for sodium-ion batteries. However, Ni3Co6S8 yolk shell nanopowder (Ni3Co6S8-YS) without pitch-derived carbon demonstrated a continuous decrease in capacity during charging and discharging. The superior sodium-ion storage properties of Ni3Co6S8@C-YS were attributed to the pitchderived carbon, which effectively adjusted the size and distribution of nanocrystals. The carbon-coated yolk-shell microspheres proposed here hold potential for various metal chalcogenide compounds and can be applied to various fields, including the energy storage field.

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Fabrication of Polymer Composite with Enhanced Insulation and Mechanical Properties using Aluminum Borate Nanowhiskers
Junhyeok Choi, Sangin Lee, Kiho Song, Taekyung Kim, Changui Ahn
J Powder Mater. 2023;30(4):356-362.   Published online August 1, 2023
DOI: https://doi.org/10.4150/KPMI.2023.30.4.356
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AbstractAbstract PDF

Inorganic-organic composites find extensive application in various fields, including electronic devices and light-emitting diodes. Notably, encapsulation technologies are employed to shield electronic devices (such as printed circuit boards and batteries) from stress and moisture exposure while maintaining electrical insulation. Polymer composites can be used as encapsulation materials because of their controllable mechanical and electrical properties. In this study, we propose a polymer composite that provides good electrical insulation and enhanced mechanical properties. This is achieved by using aluminum borate nanowhiskers (ABOw), which are fabricated using a facile synthesis method. The ABOw fillers are created via a hydrothermal method using aluminum chloride and boric acid. We confirm that the synthesis occurs in various morphologies based on the molar ratio. Specifically, nanowhiskers are synthesized at a molar ratio of 1:3 and used as fillers in the composite. The fabricated ABOw/epoxy composites exhibit a 48.5% enhancement in mechanical properties, similar to those of pure epoxy, while maintaining good electrical insulation.


Journal of Powder Materials : Journal of Powder Materials